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Manganese(III)-mediated alkenyl Csp2–P bond formation from the reaction of β-nitrostyrenes with dialkyl phosphites.
(Royal society of chemistry, 2015-03-17) Xue, J.F.; Zhou, S.F.; Liu, Y.Y.; Pan, X.; Zou, J.P.; Asekun, O.T.
Mn(OAc)3-mediated tandem phosphonyl radical addition to β-nitrostyrenes followed by denitration to form (E)-2-alkenyl phosphonates in good yield is described.