Mechanism of nucleophilic substitution reactions of 4-(4ˊ-nitro)phenylnitrobenzofurazan ether with aniline in acetonitrile
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Date
2017-08-02
Authors
Gbayo, K.
Isanbor, C.
Lobb, K.
Oloba-Whenu, O.
Journal Title
Journal ISSN
Volume Title
Publisher
De Gruyter
Abstract
Rate constants and activation parameters obtained for the nucleophilic aromatic substitution reactions (SNAr)
of 4-substitutedphenoxy-7-nitrobenzoxadiazole (1) with aniline in acetonitrile at varying temperature using
Nuclear Magnetic Resonance (NMR) techniques were reported. These results were compared with the theoretical study which identifies transformations and intermediates using Density Functional Theory (DFT).
Description
Keywords
Research Subject Categories::NATURAL SCIENCES::Chemistry::Theoretical chemistry::Quantum chemistry , Nucleophilic aromatic substitution , DFT , NMR
Citation
Gbayo, K., Isanbor, C., Lobb, K., & Oloba-Whenu, O. (2017). Mechanism of nucleophilic substitution reactions of 4-(4ˊ-nitro) phenylnitrobenzofurazan ether with aniline in acetonitrile. Physical Sciences Reviews, 2(10).