Sulphur-based directed benzylic metallations: lithiations of alkylarenesulphonates
| dc.contributor.author | Alo, B.I. | |
| dc.contributor.author | Familoni, O.B. | |
| dc.contributor.author | Marsais, F. | |
| dc.contributor.author | Queguiner, G. | |
| dc.date.accessioned | 2019-09-05T09:57:38Z | |
| dc.date.available | 2019-09-05T09:57:38Z | |
| dc.date.issued | 1990 | |
| dc.description.abstract | Benzylic anions (6) are obtained by regio-specific lithiations of ethyl 2-methylbenzenesulphonates. Evidence for the presence of the ethyl 2-lithiomethylbenzenesulphonates was obtained by efficient quenching studies with a range of electrophiles. Lithiations of the 2,4-dimethyl compound (9) gave the 2-lithiomethyl anion only, indicative of a predominant co-ordination mechanism in the lithiations. | en_US |
| dc.identifier.citation | Alo, B. I., Familoni, O. B., Marsais, F., & Queguiner, G. (1990). Sulphur-based directed benzylic metallations: lithiations of alkylarenesulphonates. Journal of the Chemical Society, Perkin Transactions 1, (6), 1611-1614. | en_US |
| dc.identifier.uri | https://ir.unilag.edu.ng/handle/123456789/5167 | |
| dc.language.iso | en | en_US |
| dc.publisher | pubs.rsc.org | en_US |
| dc.subject | Research Subject Categories::NATURAL SCIENCES::Chemistry::Organic chemistry::Organic synthesis | en_US |
| dc.title | Sulphur-based directed benzylic metallations: lithiations of alkylarenesulphonates | en_US |
| dc.type | Article | en_US |