Sulphur-based directed benzylic metallations: lithiations of alkylarenesulphonates

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dc.contributor.authorAlo, B.I.
dc.contributor.authorFamiloni, O.B.
dc.contributor.authorMarsais, F.
dc.contributor.authorQueguiner, G.
dc.date.accessioned2019-08-30T08:21:48Z
dc.date.available2019-08-30T08:21:48Z
dc.date.issued1990
dc.description.abstractBenzylic anions (6) are obtained by regio-specific lithiations of ethyl 2-methylbenzenesulphonates. Evidence for the presence of the ethyl 2-lithiomethylbenzenesulphonates was obtained by efficient quenching studies with a range of electrophiles. Lithiations of the 2,4-dimethyl compound (9) gave the 2-lithiomethyl anion only, indicative of a predominant co-ordination mechanism in the lithiations.en_US
dc.identifier.citationAlo, B. I., Familoni, O. B., Marsais, F., & Queguiner, G. (1990). Sulphur-based directed benzylic metallations: lithiations of alkylarenesulphonates. Journal of the Chemical Society, Perkin Transactions 1, (6), 1611-1614.en_US
dc.identifier.urihttps://ir.unilag.edu.ng/handle/123456789/4889
dc.language.isoenen_US
dc.publisherJournal of the Chemical Societyen_US
dc.subjectResearch Subject Categories::NATURAL SCIENCES::Chemistry::Organic chemistryen_US
dc.subjectBenzylic anionen_US
dc.subjectregio-specific lithiationsen_US
dc.subjectelectrophilesen_US
dc.subjectlithiationen_US
dc.subject2-lithiomethyl anionen_US
dc.titleSulphur-based directed benzylic metallations: lithiations of alkylarenesulphonatesen_US
dc.typeArticleen_US
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