Octahedral Tilting in MM′X4 Metal-Oxide Organic Layer Structures
dc.contributor.author | Vougo-Zanda, M. | |
dc.contributor.author | Anokhina, E.V. | |
dc.contributor.author | Duhovic, S. | |
dc.contributor.author | Liu, L. | |
dc.contributor.author | Wang, X. | |
dc.contributor.author | Oloba-whenu, O.A. | |
dc.contributor.author | Albright, T.A. | |
dc.contributor.author | Jacobson, A.J. | |
dc.date.accessioned | 2019-09-10T13:44:45Z | |
dc.date.available | 2019-09-10T13:44:45Z | |
dc.date.issued | 2008-04-29 | |
dc.description | Staff publication | en_US |
dc.description.abstract | Three metal-oxide organic frameworks have been synthesized and characterized: vanadium 1,4-benzenedicarboxylate, V2O2F0.6(OH)1.4(BDC)·0.4H2O (1); indium 1,4-benzenedicarboxylate, In2F2.2(OH)1.8(BDC)·1.6H2O (2); and aluminum 1,4-benzenedicarboxylate Al2F3(OH)(BDC) (3). The three-dimensional structures of 1, 2, and 3 have the same framework topology as the previously reported vanadium (III) 1,4-benzenedicarboxylate, VIII2(OH)2F2(BDC). The frameworks consist of inorganic layers constructed from corner sharing ML6 octahedra (M = V, In, Al and L = OH, F) linked by BDC ligands. The structures are related to a general class of perovskite-related layer structures with composition MM′X4. The layers show characteristic distortions that can be related to tilting of the ML6 octahedra. In particular the structure of 1 consists of O−V distances that strongly alternate along the b axis. The electronic consequences of this distortion then create a tilting of the 1,4-benzenedicarboxylate ligand about the a axis. Crystal data: 1, orthorhombic, space group Pmna, a = 7.101(2) Å, b = 3.8416(11) Å, c = 20.570(6) Å; 2, orthorhombic, space group Cmcm, a = 7.490(4) Å, b = 21.803(1) Å, c = 8.154(4) Å; 3, monoclinic, space group P21/m, a = 10.7569(8) Å, b = 6.7615(3) Å, c = 7.1291(3) Å, β = 76.02(1)°. | en_US |
dc.identifier.citation | Vougo-Zanda, M., [Et...al] (2008). Octahedral Tilting in MM′ X4 Metal-Oxide Organic Layer Structures. Inorganic chemistry, Vol.47(11), 4746-4751pp. | en_US |
dc.identifier.uri | https://ir.unilag.edu.ng/handle/123456789/5475 | |
dc.language.iso | en | en_US |
dc.publisher | American chemical society | en_US |
dc.relation.ispartofseries | Inorganic chemistry;Vol.47(1) | |
dc.subject | Research Subject Categories::NATURAL SCIENCES::Chemistry::Physical chemistry | en_US |
dc.subject | metal-oxide | en_US |
dc.subject | 1,4-benzenedicarboxylate | en_US |
dc.subject | distortions | en_US |
dc.subject | orthorhombic | en_US |
dc.title | Octahedral Tilting in MM′X4 Metal-Oxide Organic Layer Structures | en_US |
dc.type | Article | en_US |
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