GC/MS Analysis of Polyaromatic Hydrocarbons in Sediment Samples from the Niger Delta Region

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Date
2005-02
Authors
Ogah, Celina
Journal Title
Journal ISSN
Volume Title
Publisher
Elsevier Ltd
Abstract
Thirteen sediment samples from different locations in the Niger Delta region of Nigeria were analyzed for the presence of 16 polynuclear aromatic hydrocarbons (PAHs) via gas chromatography/mass spectrometry. The specific target compounds for this study included naphthalene, acenaphthylene, acenaphthene, flourene, phenanthrene, anthracene, flouranthene, pyrene, benz[a]anthracene, chrysene, benzo[b]fluoranthene, benzo[k]flouranthene, benzo[a]pyrene, benzo[ghi]perylene, dibenz[a,h]anthracene, and indeno[1,2,3-cd]pyrene. Four isotopically labeled polynuclear aromatic hydrocarbons (acanaphthene-d10, phenanthrene-d10, chrysene-d12 and perylene-d12) were used for internal standardization. All 16 PAHs were found in most of the thirteen samples with concentration ranging from 0.1 lg/kg to 28 lg/kg. It was also found that the 5 and 6-ring PAHs were present in higher concentrations than all the other compounds, indicating their high resistance to microbial degradation.
Description
Scholarly articles
Keywords
Polynuclear aromatic hydrocarbons , Niger Delta , Microbial degradation , Naphthalene , Gas chromatography-mass spectrometry , Research Subject Categories::PHARMACY
Citation
Chemosphere; 60: 990-997.