Manganese(III)-mediated direct Csp2–H radical trifluoromethylation of coumarins with sodium trifluoromethanesulfinate
dc.contributor.author | Cao, X.H. | |
dc.contributor.author | Pan, X. | |
dc.contributor.author | Zhou, P.J. | |
dc.contributor.author | Zou, J.P. | |
dc.contributor.author | Asekun, O.T. | |
dc.date.accessioned | 2019-08-23T14:52:12Z | |
dc.date.available | 2019-08-23T14:52:12Z | |
dc.date.issued | 2014-02-03 | |
dc.description.abstract | Mn(OAc)3-mediated direct Csp2–H radical trifluoromethylation of coumarins with CF3SO2Na (Langlois reagent) to afford selective 3-trifluoromethyl coumarins in moderate to good yields is described. This methodology can also be applied to the trifluoromethylation of quinolinones and pyrimidinones. | en_US |
dc.identifier.citation | Cao, X. H., Pan, X., Zhou, P. J., Zou, J. P., & Asekun, O. T. (2014). Manganese (iii)-mediated direct C sp2–H radical trifluoromethylation of coumarins with sodium trifluoromethanesulfinate. Chemical communications, 50(25), 3359-3362. | en_US |
dc.identifier.uri | https://ir.unilag.edu.ng/handle/123456789/4644 | |
dc.language.iso | en | en_US |
dc.publisher | Royal society of chemistry | en_US |
dc.subject | Research Subject Categories::NATURAL SCIENCES::Chemistry::Organic chemistry::Organic synthesis | en_US |
dc.subject | selective | en_US |
dc.subject | trifluoromethylation | en_US |
dc.subject | quinolinones | en_US |
dc.subject | pyrimidinones | en_US |
dc.title | Manganese(III)-mediated direct Csp2–H radical trifluoromethylation of coumarins with sodium trifluoromethanesulfinate | en_US |
dc.type | Article | en_US |
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